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Molecular Heterogeneity Drives Reconfigurable Nematic Liquid Crystal Drops
With few exceptions, polydispersity or molecular heterogeneity in matter tends to impede assembly Shape transformations of liquid droplets, for example, are readily understood on the basis of homogeneous material responses. Here, Yodh and Yang in IRG-3 studied drops filled with polydisperse nematic liquid crystal oligomers (NLCOs). They discovered that chain-length heterogeneity in the drops promotes reversible shape transitions to a rich variety of non-spherical morphologies with unique internal structure.
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Paramagnetic Organocobalt Capsule Reveals Xe Host-Guest Chemistry
This collaboration between Dmochowski (Seed) and Kikkawa (IRG-3) addresses a major challenge for molecular imaging with conventional MRI: the probes typically have low sensitivity and lack of responsiveness to local environment. The team developed a Co4 129Xe MRI sensor, which takes advantage of the high sensitivity of hyperpolarized 129Xe (~104 times greater signal than conventional MRI), and also has a very temperature-responsive 129Xe chemical shift.
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Shape-Shifting Lattices via Multimaterial 4D Printing
A team at the Harvard MRSEC led by Lakshminarayanan Mahadevan and Jennifer A. Lewis has created shape-shifting lattices by combining predictive design and multimaterial 4D printing.
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Building Enduring Pathways in STEM: Incorporating Traditional Ways of Knowing in Materials Research
This unique partnership between Navajo Technical University and the Harvard MRSEC builds enduring pathways for undergraduate Native American students into STEM by including traditional Navajo perspectives and methods of scientific inquiry in materials science research and education.
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Voltage Control of Optical Properties by Ionic Gating
Using a simple device structure, it has been shown that electrical control of optical properties can be achieved through electrochemical hydrogen gating, sourced from moisture in the air.
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A hydrogen-bonded framework toolkit for molecular structure determination
MRSEC investigators reported that a versatile toolkit of guanidinium organosulfonate hydrogen-bonded host frameworks can form inclusion compounds with complex “stubborn” molecules that cannot be crystallized or form suitable single crystals for X-ray diffraction analysis by themselves, enabling determination of their molecular structure.
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Test-Tube Gemstones
The research funded by this grant has enabled to develop a conceptually new approach to colloidal self-assembly that borrows no material from biology and entirely relies on the innate charge that any colloidal particle develops in water.
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Voltage Control of Magnetism above Room Temperature in epitaxial SrCo1-xFexO3-δ
Searching for new materials and phenomena to enable voltage control of magnetism and magnetic properties holds compelling interest for the development of low-power non-volatile memory devices. Here, we report on a non-volatile ON/OFF voltage control of magnetism in thin films of an oxide, SrCo1-xFexO3-δ (SCFO).
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