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Strain Superlattice of Graphene on Nanospheres
Strain engineering two-dimensional (2D) materials provides a new way to tailor electronic bandstructures and access novel electronic devices. A key route to strain 2D materials, such as graphene, is via underlying nanostructured substrates.
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Reaching Underserved Audiences by Bringing Science to a Local Food Pantry
Not all members of our community have the time or resources to attend science outreach events. To reach some of those people, the Wisconsin MRSEC conducts its engaging, hands-on science activities to a local food pantry. Customers can wait up to 90 minutes at the food pantry, providing ample time for educational activities for kids, their parents, and other curious adult visitors.
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Optically Reconfigurable Dielectrics in Ultra-Thin Transistors
In this work, molecular self-assembly of highly polarizable PAE molecules was used to create reconfigurable dielectric layers whose capacitance changes with illumination. Upon ultraviolet optical illumination, the PAE molecules undergo a photoisomerization from an extended trans geometry to a compact cis geometry, which can be reversed upon illumination at longer wavelengths.
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Improving the Ambient Stability of Chemically Reactive 2D Materials
To enable ambient processing and study of indium selenide, NU-MRSEC IRG-1 has developed a mixed-dimensional organic/inorganic passivation scheme based on n-methyl-2-pyrrilodone (NMP) seeded atomic layer deposited (ALD) alumina that provides a pinhole-free encapsulation layer that preserves the intrinsic electronic properties of the underlying InSe.
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Network Analysis of Synthesizable Materials Discovery
Materials synthesis is a complex process that depends not only on thermodynamic stability, but also on kinetic factors, advances in synthesis techniques, and the availability of precursors. This complexity makes the development of a general theory for predicting synthesizability extremely difficult.
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Processing 2D Porous Polymers into Membranes via Exfoliation
The NU-MRSEC Super-Seed team has developed a method to process imine-linked 2D COF powders into thin films via reversible exfoliation. The COF powder is treated with strong acids, which causes each layer to become positively charged. This charged form is exfoliated in solvents with gentle sonication, which provides a suspension of nanosheets.
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Designing Biomaterials Using High-Throughput Directed Evolution
Traditional design approaches are insufficient for exploring the vast phase space available to protein-based biomaterials. This NU-MRSEC seed-funded project is developing a platform for biomaterials design using directed evolution, which combines genetic mutation and protein synthesis with high-throughput materials characterization.
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NSF-MRSEC Booth at the International Materials Research Congress
The NSF-MRSEC booth was featured at the XXVII International Materials Research Congress (IMRC) in Cancun, Mexico on August 19-24, 2018 to increase awareness, promote international collaboration, and broaden participation from traditionally underrepresented groups in the National Science Foundation Materials Research Science and Engineering Center (NSF-MRSEC) program.
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ABC Micelleplexes: Precise Compaction and High Colloidal Stability
In this work, the complexation of ABC micelles with a model semiflexible polyion, DNA, is systematically investigated to correlate the structure of the micelle with the properties of the resulting “micelleplexes”.
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Subatomic Channeling and Spiraling Electron Beams in Crystals
Using analytical aberration-corrected scanning transmission electron microscopy (STEM), we studied the behavior of the electron probe propagating in SrTiO3 at sub-atomic length scales.
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